Azulenophenanthrenes from 2,2′‐Di(arylethynyl)biphenyls through CC Bond Cleavage of a Benzene Ring | Zendy

Matsuda Takanori | Zendy; Goya Tsuyoshi | Zendy; Liu Lantao | Zendy; Sakurai Yusuke | Zendy; Watanuki Shoichi | Zendy; Ishida Naoki | Zendy; Murakami Masahiro | Zendy

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Azulenophenanthrenes from 2,2′‐Di(arylethynyl)biphenyls through CC Bond Cleavage of a Benzene Ring

Author(s) -

Matsuda Takanori,

Goya Tsuyoshi,

Liu Lantao,

Sakurai Yusuke,

Watanuki Shoichi,

Ishida Naoki,

Murakami Masahiro

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300570

Subject(s) - azulene , benzene , cleavage (geology) , ring (chemistry) , chemistry , bond cleavage , medicinal chemistry , catalysis , platinum , stereochemistry , photochemistry , organic chemistry , materials science , fracture (geology) , composite material

From six to seven : 2,2′‐Di(arylethynyl)biphenyls undergo a skeletal rearrangement in the presence of a platinum(II) catalyst to afford polycyclic aromatic compounds containing an azulene unit. The reaction involves CC bond cleavage of a benzene ring, which expands into a seven‐membered ring.

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