Weak Arene CH⋅⋅⋅O Hydrogen Bonding in Palladium‐Catalyzed Arylation and Vinylation of Lactones | Zendy

Huang Zhiyan | Zendy; Chen Zuliang | Zendy; Lim Li Hui | Zendy; Quang Gia Chuong Phan | Zendy; Hirao Hajime | Zendy; Zhou Jianrong Steve | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Weak Arene CH⋅⋅⋅O Hydrogen Bonding in Palladium‐Catalyzed Arylation and Vinylation of Lactones

Author(s) -

Huang Zhiyan,

Chen Zuliang,

Lim Li Hui,

Quang Gia Chuong Phan,

Hirao Hajime,

Zhou Jianrong Steve

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300481

Subject(s) - palladium , stereocenter , catalysis , chemistry , hydrogen bond , hydrogen , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry , molecule , enantioselective synthesis

Weak force in action : In the title reaction, the palladium catalyst (see figure, left) uses weak CH⋅⋅⋅O hydrogen bonding to control the absolute configuration of the new stereocenter. A similar palladium catalyst (right) used conventional NH⋅⋅⋅O hydrogen bonding to guide stereoselection.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research