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Ligand‐Directed Control over Crystal Structures of Inorganic–Organic Frameworks and Formation of Solid Solutions
Author(s) -
Yeung Hamish H.M.,
Li Wei,
Saines Paul J.,
Köster Thomas K. J.,
Grey Clare P.,
Cheetham Anthony K.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300440
Subject(s) - ternary operation , synchrotron , crystallography , solid state , powder diffraction , solid solution , diffraction , ligand (biochemistry) , computer science , chemistry , materials science , physics , organic chemistry , optics , biochemistry , receptor , programming language
Grounded in fact : Inorganic–organic frameworks with 3D Li–O–Li connectivity can form solid solutions through mechanochemical synthesis. High‐resolution synchrotron powder X‐ray diffraction and cross‐polarization solid‐state NMR spectroscopy demonstrate complete ligand mixing in the resulting binary and ternary systems (see picture for trends in unit cell volume ( V ) of the ternary system {Li 2 (suc) x (mal) y (met) z } n ).