Supramolecular Ladders from Dimeric Cucurbit[6]uril | Zendy

Wittenberg James B. | Zendy; Zavalij Peter Y. | Zendy; Isaacs Lyle | Zendy

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Supramolecular Ladders from Dimeric Cucurbit[6]uril

Author(s) -

Wittenberg James B.,

Zavalij Peter Y.,

Isaacs Lyle

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300404

Subject(s) - supramolecular chemistry , chemistry , cucurbituril , random hexamer , crystallography , cationic polymerization , stereochemistry , supramolecular assembly , combinatorial chemistry , crystal structure , polymer chemistry

Climbing the cucurbit ladder : Cucurbit[6]uril dimers (connected gray cylinders; see scheme) were prepared by condensation of glycoluril hexamer with the appropriate tetraaldehydes. The self‐assembly process between these dimers and oligoviologen compounds (blue) in water leads to a supramolecular ladder with the dimensions and molecular weight typical of small proteins.

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