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Telluronium Ions as σ‐Acceptor Ligands
Author(s) -
Lin TzuPin,
Gabbaï François P.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300337
Subject(s) - lone pair , computer science , palladium , element (criminal law) , ligand (biochemistry) , group (periodic table) , information retrieval , world wide web , chemistry , molecule , political science , organic chemistry , law , biochemistry , receptor , catalysis
A duel between lone pairs: A telluronium cation has been successfully installed in the coordination sphere of a palladium(II) complex. Despite the presence of a lone pair centered on the Group 16 element, the telluronium ion acts as a Z‐ligand and accepts a d‐electron pair from the palladium atom.
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