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Synthesis of Functionalizable and Degradable Polymers by Ring‐Opening Metathesis Polymerization
Author(s) -
Fishman Joshua M.,
Kiessling Laura L.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300293
Subject(s) - romp , polymerization , metathesis , ring opening metathesis polymerisation , polymer , monomer , olefin metathesis , polymer science , computer science , chemistry , polymer chemistry , organic chemistry
ROMP : A heterobicyclic olefin containing an oxazinone core is a new substrate for the ring‐opening metathesis polymerization (ROMP). The polymers produced undergo degradation when exposed to either acidic or basic conditions. Furthermore, a monomer that can be readily diversified to access degradable polymers bearing tailored functionality was developed.