Phosphacycles as Building Blocks for Main Group Cages | Zendy

Townsend Nell S. | Zendy; Shadbolt Sam R. | Zendy; Green Michael | Zendy; Russell Christopher A. | Zendy

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Phosphacycles as Building Blocks for Main Group Cages

Author(s) -

Townsend Nell S.,

Shadbolt Sam R.,

Green Michael,

Russell Christopher A.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300202

Subject(s) - pnictogen , cationic polymerization , cage , carbene , group (periodic table) , chemistry , carbon fibers , medicinal chemistry , stereochemistry , polymer chemistry , materials science , organic chemistry , mathematics , combinatorics , physics , catalysis , composite material , superconductivity , quantum mechanics , composite number

Cationic pnictogen/carbon cages are formed from reaction of 2,4,6‐tri‐ tert ‐butyl‐1,3,5‐triphosphabenzene with the carbene mimics EX 2 + (E=P, As). For E=P, 1,4‐addition to the hetereoaromatic compound is observed, whereas for E=As, cage complexes are formed.

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