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Phosphacycles as Building Blocks for Main Group Cages
Author(s) -
Townsend Nell S.,
Shadbolt Sam R.,
Green Michael,
Russell Christopher A.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300202
Subject(s) - pnictogen , cationic polymerization , cage , carbene , group (periodic table) , chemistry , carbon fibers , medicinal chemistry , stereochemistry , polymer chemistry , materials science , organic chemistry , mathematics , combinatorics , physics , catalysis , composite material , superconductivity , quantum mechanics , composite number
Cationic pnictogen/carbon cages are formed from reaction of 2,4,6‐tri‐ tert ‐butyl‐1,3,5‐triphosphabenzene with the carbene mimics EX 2 + (E=P, As). For E=P, 1,4‐addition to the hetereoaromatic compound is observed, whereas for E=As, cage complexes are formed.