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Silver‐Catalyzed Nitrogenation of Alkynes: A Direct Approach to Nitriles through CC Bond Cleavage
Author(s) -
Shen Tao,
Wang Teng,
Qin Chong,
Jiao Ning
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300193
Subject(s) - cleavage (geology) , catalysis , bond cleavage , chemistry , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , materials science , fracture (geology) , composite material
Three in one blow! A novel direct transformation of alkynes into nitriles by a silver‐catalyzed nitrogenation reaction through CC bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.