Regio‐ and Chemoselective CH Chlorination/Bromination of Electron‐Deficient Arenes by Weak Coordination and Study of Relative Directing‐Group Abilities | Zendy

Sun Xiuyun | Zendy; Shan Gang | Zendy; Sun Yonghui | Zendy; Rao Yu | Zendy

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Regio‐ and Chemoselective CH Chlorination/Bromination of Electron‐Deficient Arenes by Weak Coordination and Study of Relative Directing‐Group Abilities

Author(s) -

Sun Xiuyun,

Shan Gang,

Sun Yonghui,

Rao Yu

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300176

Subject(s) - halogenation , reactivity (psychology) , chemistry , group (periodic table) , chemoselectivity , range (aeronautics) , field (mathematics) , combinatorial chemistry , medicinal chemistry , catalysis , organic chemistry , engineering , mathematics , medicine , alternative medicine , pathology , pure mathematics , aerospace engineering

It's all relative : A practical and efficient Pd II ‐catalyzed regio‐ and chemoselective chlorination/bromination has been developed for the facile synthesis of a broad range of aromatic chlorides. The reaction demonstrates excellent reactivity, good functional‐group tolerance, and high yields. A preliminary study was conducted to evaluate relative directing‐group abilities of various functionalities.

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