Rhodium‐Catalyzed Asymmetric Arylative Cyclization of  meso ‐1,6‐Dienynes Leading to Enantioenriched  cis ‐Hydrobenzofurans | Zendy

He ZhiTao | Zendy; Tian Bing | Zendy; Fukui Yuki | Zendy; Tong Xiaofeng | Zendy; Tian Ping | Zendy; Lin GuoQiang | Zendy

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Rhodium‐Catalyzed Asymmetric Arylative Cyclization of meso ‐1,6‐Dienynes Leading to Enantioenriched cis ‐Hydrobenzofurans

Author(s) -

He ZhiTao,

Tian Bing,

Fukui Yuki,

Tong Xiaofeng,

Tian Ping,

Lin GuoQiang

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300137

Subject(s) - desymmetrization , enantioselective synthesis , intramolecular force , chemistry , stereochemistry , bifunctional , organocatalysis , catalysis , combinatorial chemistry , organic chemistry

In tandem : The title reaction of cyclohexadienone‐containing meso ‐1,6‐dienynes with arylboronic acids through a tandem arylrhodation/conjugate addition sequence has been realized, and provides a novel approach to the enantioenriched cis ‐hydrobenzofurans with both excellent yields and enantioselectivities. binap=2,2′‐bis(diphenylphosphanyl)‐1,1′‐binaphthyl, Boc= tert ‐butoxycarbonyl.

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