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Iron‐Catalyzed, Atom‐Economical, Chemo‐ and Regioselective Alkene Hydroboration with Pinacolborane
Author(s) -
Zhang Lei,
Peng Dongjie,
Leng Xuebing,
Huang Zheng
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201210347
Subject(s) - hydroboration , alkene , olefin fiber , regioselectivity , catalysis , chemistry , selectivity , metal , organic chemistry
Precious iron : A new PNN iron complex has been developed for use in an iron‐catalyzed alkene hydroboration reaction under mild conditions. The environmentally friendly and earth‐abundant iron catalyst system is superior to precious‐metal systems in terms of efficiency and selectivity for α‐olefin hydroborations with pinacolborane.