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The Impact of Palladium(II) Reduction Pathways on the Structure and Activity of Palladium(0) Catalysts
Author(s) -
Wei Carolyn S.,
Davies Geraint H. M.,
Soltani Omid,
Albrecht Jacob,
Gao Qi,
Pathirana Charles,
Hsiao Yi,
Tummala Srinivas,
Eastgate Martin D.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201210252
Subject(s) - palladium , catalysis , borylation , chemistry , computer science , combinatorial chemistry , organic chemistry , alkyl , aryl
Two roads diverged : The mechanism of in situ Pd II catalyst activation to generate an active {L n Pd 0 } catalyst from an air‐stable Pd II precursor was examined using the standard conditions of a Miyaura borylation reaction. Two pathways for catalyst activation exist under these conditions, producing two structurally and chemically distinct {L n Pd 0 } complexes (see scheme).