The Impact of Palladium(II) Reduction Pathways on the Structure and Activity of Palladium(0) Catalysts | Zendy

Wei Carolyn S. | Zendy; Davies Geraint H. M. | Zendy; Soltani Omid | Zendy; Albrecht Jacob | Zendy; Gao Qi | Zendy; Pathirana Charles | Zendy; Hsiao Yi | Zendy; Tummala Srinivas | Zendy; Eastgate Martin D. | Zendy

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The Impact of Palladium(II) Reduction Pathways on the Structure and Activity of Palladium(0) Catalysts

Author(s) -

Wei Carolyn S.,

Davies Geraint H. M.,

Soltani Omid,

Albrecht Jacob,

Gao Qi,

Pathirana Charles,

Hsiao Yi,

Tummala Srinivas,

Eastgate Martin D.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201210252

Subject(s) - palladium , catalysis , borylation , chemistry , computer science , combinatorial chemistry , organic chemistry , alkyl , aryl

Two roads diverged : The mechanism of in situ Pd II catalyst activation to generate an active {L n Pd 0 } catalyst from an air‐stable Pd II precursor was examined using the standard conditions of a Miyaura borylation reaction. Two pathways for catalyst activation exist under these conditions, producing two structurally and chemically distinct {L n Pd 0 } complexes (see scheme).

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