Functional‐Group Tolerance in Frustrated Lewis Pairs: Hydrogenation of Nitroolefins and Acrylates | Zendy

Greb Lutz | Zendy; Daniliuc ConstantinGabriel | Zendy; Bergander Klaus | Zendy; Paradies Jan | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Functional‐Group Tolerance in Frustrated Lewis Pairs: Hydrogenation of Nitroolefins and Acrylates

Author(s) -

Greb Lutz,

Daniliuc ConstantinGabriel,

Bergander Klaus,

Paradies Jan

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201210175

Subject(s) - frustrated lewis pair , reactivity (psychology) , hydride , lewis acids and bases , nucleophile , chemistry , functional group , database , computer science , hydrogen , organic chemistry , medicine , catalysis , polymer , alternative medicine , pathology

Weak Lewis acid for high nucleophilicity : Hydridoborate derived from B(2,6‐F 2 C 6 H 3 ) 3 shows significant hydride character. Solid‐state and solution structure analysis revealed a dihydrogen‐bonded aggregate. The new frustrated Lewis pair was applied in the hydrogenation of nitroolefins and acrylates (see scheme; EWG=electron‐withdrawing group). The decreased Lewis acidity provides higher reactivity and functional‐group tolerance.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research