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Pressure‐Induced Water Insertion in Synthetic Clays
Author(s) -
You Shujie,
Kunz Daniel,
Stöter Matthias,
Kalo Hussein,
Putz Bernd,
Breu Josef,
Talyzin Alexandr V.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201210060
Subject(s) - synchrotron , diamond anvil cell , phase transition , diffraction , materials science , layer (electronics) , phase (matter) , in situ , crystallography , chemistry , mineralogy , analytical chemistry (journal) , composite material , thermodynamics , optics , chromatography , organic chemistry , physics
A high‐pressure study of a synthetic smectite (Na‐fluorohectorite) immersed in liquid media was performed using in situ synchrotron X‐ray diffraction in a diamond anvil cell. A reversible phase transition because of the insertion of an additional water layer was observed for this material at 1.7 GPa. No similar transition was found when methanol was used as a pressure medium (see picture).

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