Assembly of a  cyclo ‐Tetrastibinotetraphosphonium Tetracation by Reductive Elimination | Zendy

Chitnis Saurabh S. | Zendy; Carpenter YuenYing | Zendy; Burford Neil | Zendy; McDonald Robert | Zendy; Ferguson Michael J. | Zendy

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Assembly of a cyclo ‐Tetrastibinotetraphosphonium Tetracation by Reductive Elimination

Author(s) -

Chitnis Saurabh S.,

Carpenter YuenYing,

Burford Neil,

McDonald Robert,

Ferguson Michael J.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201210012

Subject(s) - reductive elimination , chemistry , computer science , service (business) , redox , combinatorial chemistry , world wide web , library science , organic chemistry , catalysis , business , marketing

Square deal : Reactions of SbF 3 with Me 3 SiOSO 2 CF 3 produce Sb 3+ and [Sb‐F] 2+ cations, which form complexes with two or three Me 3 P ligands. Subsequent reductive elimination of diphosphonium or fluorophosphonium cations from the complexes give the folded square cyclo ‐[(Me 3 P) 4 Sb 4 ][OTf] 4 . Formation of the tetracation framework reveals new redox chemistry for Sb.

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