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Gold‐Catalyzed Cyclization/Oxidative [3+2] Cycloadditions of 1,5‐Enynes with Nitrosobenzenes without Additional Oxidants
Author(s) -
Chen ChunHao,
Tsai YenChing,
Liu RaiShung
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201209850
Subject(s) - yield (engineering) , chemistry , catalysis , combinatorial chemistry , oxidative phosphorylation , medicinal chemistry , organic chemistry , biochemistry , physics , thermodynamics
Golden control : The title reaction (see scheme) proceeds with high stereocontrol to generate the heterocyclic products in good yield. Experiments to probe the mechanism were performed.