Tungsten‐Based Catalysts for Selective Deoxygenation | Zendy

Gosselink Robert W. | Zendy; Stellwagen Daniel R. | Zendy; Bitter Johannes H. | Zendy

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Tungsten‐Based Catalysts for Selective Deoxygenation

Author(s) -

Gosselink Robert W.,

Stellwagen Daniel R.,

Bitter Johannes H.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201209809

Subject(s) - deoxygenation , decarbonylation , hydrodeoxygenation , catalysis , decarboxylation , tungsten , chemistry , hydrogen , photochemistry , organic chemistry , selectivity

On the tip of the tung(sten) : The title catalysts selectively perform deoxygenation of vegetable‐oil‐based feeds by either decarboxylation/decarbonylation or hydrodeoxygenation (HDO) pathways, depending on the dominant tungsten phase (WO 3 and W 2 C). The process upgrades vegetable‐oil‐based feeds, under a hydrogen atmosphere, to high‐value olefinic products, thus providing a significant advantage over other types of deoxygenation catalysts.

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