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Maximizing Coordinative and Electronic Unsaturation: Three‐Coordinate Dicationic Platinum Complexes
Author(s) -
Braunschweig Holger,
Brenner Peter,
Dewhurst Rian D.,
JimenezHalla J. Oscar C.,
Kupfer Thomas,
Rais Daniela,
Uttinger Katharina
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201209717
Subject(s) - degree of unsaturation , platinum , chemistry , phosphine , cationic polymerization , combinatorial chemistry , computer science , stereochemistry , information retrieval , world wide web , organic chemistry , catalysis
Halide abstraction from cationic base‐stabilized borylene complexes led to extremely electronically and coordinatively unsaturated platinum complexes. The formally 14‐electron borylene complexes show no agostic interactions with the phosphine ligands, and only small Lewis donor ligands could be added to the Pt center.