Molecular Dynamics and Ligand Exchange in Magnesium Complexes: Evidence for both Dissociative and Associative Ligand Exchange | Zendy

Chisholm Malcolm H. | Zendy; Choojun Kittisak | Zendy; Chow Albert S. | Zendy; Fraenkel Gideon | Zendy

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Molecular Dynamics and Ligand Exchange in Magnesium Complexes: Evidence for both Dissociative and Associative Ligand Exchange

Author(s) -

Chisholm Malcolm H.,

Choojun Kittisak,

Chow Albert S.,

Fraenkel Gideon

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201209542

Subject(s) - associative substitution , dissociative , chemistry , tetrahydrofuran , swap (finance) , computer science , polymerization , associative property , ligand (biochemistry) , world wide web , combinatorial chemistry , information retrieval , psychology , catalysis , business , organic chemistry , biochemistry , polymer , receptor , mathematics , finance , psychiatry , solvent , pure mathematics

Making a swap : The titled studies provide substantial evidence for the kinetically labile Mg 2+ ion reacting through both a dissociative (see scheme; thf=tetrahydrofuran) and an associative interchange mechanism. The findings are particularly relevant to the reactions involving [LMg n Bu(thf)] and rac‐ lactide in ring‐opening polymerization reactions.

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