Premium
Versatile Reactivity of Rhodium–Iminocarbenes Derived from N ‐Sulfonyl Triazoles
Author(s) -
Gulevich Anton V.,
Gevorgyan Vladimir
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201209338
Subject(s) - sulfonyl , rhodium , reactivity (psychology) , carbene , chemistry , triazole , combinatorial chemistry , stereochemistry , organic chemistry , catalysis , alternative medicine , pathology , medicine , alkyl
The migrations of different groups to the metal–carbene center of Rh II ‐stabilized iminocarbenes that were derived from N ‐sulfonyl triazoles are discussed (see scheme). The reactivity of these Rh‐iminocabenes can be tuned easily by variation of substituents on the parent triazole.