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Formyl Azide: Properties and Solid‐State Structure
Author(s) -
Zeng Xiaoqing,
Bernhardt Eduard,
Beckers Helmut,
Banert Klaus,
Hagedorn Manfred,
Liu Hailiang
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201209288
Subject(s) - azide , raman spectroscopy , solid state , chemistry , isocyanate , photochemistry , photodissociation , polymer chemistry , organic chemistry , polyurethane , physics , optics
The simplest acyl azide , HC(O)N 3 , has been prepared as the neat substance and characterized by IR and Raman spectroscopy and low‐temperature X‐ray crystallography (see solid‐state structure; C white, H gray, N blue, O red). Photolysis of the azide in CO‐doped solid noble‐gas matrices furnished the first experimental proof of the elusive parent acyl isocyanate HC(O)NCO.
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