Well Known or New? Synthesis and Structure Assignment of Binary C 2 N 14  Compounds Reinvestigated | Zendy

Banert Klaus | Zendy; Richter Sebastian | Zendy; Schaarschmidt Dieter | Zendy; Lang Heinrich | Zendy

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Well Known or New? Synthesis and Structure Assignment of Binary C 2 N 14 Compounds Reinvestigated

Author(s) -

Banert Klaus,

Richter Sebastian,

Schaarschmidt Dieter,

Lang Heinrich

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201209170

Subject(s) - closure (psychology) , binary number , computer science , tetrazole , service (business) , information retrieval , chemistry , combinatorial chemistry , stereochemistry , mathematics , arithmetic , business , marketing , economics , market economy

Rapid ring closure transforms the tetraazide 1 , which was thought to have been characterized at room temperature in 1961 and 2009, into the tetrazole 2 . Consequently, the previously synthesized compounds actually are identical with heterocycle 2 , which was also prepared by a third method in 2011. After its generation at low temperature, the open‐chain compound 1 and its cyclization reaction have now been analyzed for the first time.

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