Cross‐Metathesis/Iridium(I)‐catalyzed Allylic Etherification Strategy: (Iterative) Catalytic Asymmetric Synthesis of  syn‐  and  anti ‐1,2‐Diols | Zendy

Kim Dongeun | Zendy; Lee Jae Seung | Zendy; Kong Suk Bin | Zendy; Han Hyunsoo | Zendy

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Cross‐Metathesis/Iridium(I)‐catalyzed Allylic Etherification Strategy: (Iterative) Catalytic Asymmetric Synthesis of syn‐ and anti ‐1,2‐Diols

Author(s) -

Kim Dongeun,

Lee Jae Seung,

Kong Suk Bin,

Han Hyunsoo

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201209112

Subject(s) - iridium , catalysis , computer science , metathesis , combinatorial chemistry , allylic rearrangement , control (management) , chemistry , organic chemistry , polymerization , polymer , artificial intelligence

Protection optional : The title reaction strategy is used to prepare 1,2‐diols with complete control of their absolute and relative stereochemistry. The method tolerates free and Me‐/Bn‐/TBS‐protected alcohol functionalities, and its diastereoselectivity is controlled by the stereochemistry of the ligands/catalysts used. Protected 1,2,3,4‐tetraols are synthesized by iterative applications of the strategy.

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