Reactivity of a Metastable Cobalt(III) Trisulfide Complex: Multiple CH Functionalization of  p ‐Xylene and Disulfides to Afford Photofunctional Cobalt Complexes | Zendy

Maruyama Masashi | Zendy; König Matthias | Zendy; Guldi Dirk M. | Zendy; Nakamura Eiichi | Zendy; Matsuo Yutaka | Zendy

Premium

Reactivity of a Metastable Cobalt(III) Trisulfide Complex: Multiple CH Functionalization of p ‐Xylene and Disulfides to Afford Photofunctional Cobalt Complexes

Author(s) -

Maruyama Masashi,

König Matthias,

Guldi Dirk M.,

Nakamura Eiichi,

Matsuo Yutaka

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201209046

Subject(s) - reactivity (psychology) , cobalt , surface modification , chemistry , metastability , combinatorial chemistry , organic chemistry , medicine , alternative medicine , pathology

Unprecedented reactivity of a metastable cobalt trisulfide complex has been observed, and several direct CS bond formation reactions by CH functionalization were developed. These reactions produced a series of photofunctional motifs of sulfur‐rich cobalt complexes (see picture). The measured photophysical properties of these complexes suggest promising molecular designs for photocurrent generating materials.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research