Redox‐Controlled Selectivity of CH Activation in the Oxidative Cross‐Coupling of Arenes | Zendy

Cambeiro Xacobe C. | Zendy; Boorman Tanya C. | Zendy; Lu Pengfei | Zendy; Larrosa Igor | Zendy

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Redox‐Controlled Selectivity of CH Activation in the Oxidative Cross‐Coupling of Arenes

Author(s) -

Cambeiro Xacobe C.,

Boorman Tanya C.,

Lu Pengfei,

Larrosa Igor

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201209007

Subject(s) - selectivity , chemistry , stoichiometry , oxidative phosphorylation , redox , oxidative coupling of methane , photochemistry , oxidative addition , combinatorial chemistry , stereochemistry , catalysis , inorganic chemistry , organic chemistry , biochemistry

Gold brings us together : Taking advantage of the orthogonal reactivities of Au I and Au III towards CH activation of electron‐poor and electron‐rich arenes, respectively, a novel approach for the synthesis of biaryls through double CH activation is proposed. Stoichiometric studies demonstrate that these oxidative couplings occur with high selectivity at low temperature.

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