IR Spectrum and Structure of a Protonated Disilane: Probing the SiHSi Proton Bridge | Zendy

Savoca Marco | Zendy; Langer Judith | Zendy; Dopfer Otto | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

IR Spectrum and Structure of a Protonated Disilane: Probing the SiHSi Proton Bridge

Author(s) -

Savoca Marco,

Langer Judith,

Dopfer Otto

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201208958

Subject(s) - disilane , protonation , bridge (graph theory) , polysilane , photodissociation , characterization (materials science) , proton , chemistry , spectroscopy , infrared spectroscopy , crystallography , physics , nanotechnology , photochemistry , materials science , silicon , organic chemistry , nuclear physics , quantum mechanics , ion , polymer , medicine

Structure elucidation : The IR spectrum of the protonated disilane Si 2 H 7 + has been derived by resonant IR photodissociation spectroscopy of weakly bound Si 2 H 7 + ⋅Ne clusters (see picture). Analysis of the spectra provides the first characterization of this fundamental polysilane cation and direct evidence for the nonlinear SiHSi proton bridge with a three‐center two‐electron bond.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research