Copper‐Catalyzed Oxidative Coupling of Alkenes with Aldehydes: Direct Access to α,β‐Unsaturated Ketones | Zendy

Wang Jing | Zendy; Liu Chao | Zendy; Yuan Jiwen | Zendy; Lei Aiwen | Zendy

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Copper‐Catalyzed Oxidative Coupling of Alkenes with Aldehydes: Direct Access to α,β‐Unsaturated Ketones

Author(s) -

Wang Jing,

Liu Chao,

Yuan Jiwen,

Lei Aiwen

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201208920

Subject(s) - oxidative coupling of methane , catalysis , chemistry , copper , alkene , oxidative phosphorylation , coupling (piping) , electron transfer , coupling reaction , organic chemistry , photochemistry , materials science , biochemistry , metallurgy

Let's get radical : The first copper‐catalyzed oxidative coupling of alkenes and aldehydes was developed. Various aldehydes were utilized as substrates to construct α,β‐unsaturated ketones. A preliminary mechanistic study indicated that this reaction is likely to proceed through a single‐electron transfer.

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