Complexity from Simplicity: Tricyclic Aziridines from the Rearrangement of Pyrroles by Batch and Flow Photochemistry | Zendy

Maskill Katie G. | Zendy; Knowles Jonathan P. | Zendy; Elliott Luke D. | Zendy; Alder Roger W. | Zendy; BookerMilburn Kevin I. | Zendy

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Complexity from Simplicity: Tricyclic Aziridines from the Rearrangement of Pyrroles by Batch and Flow Photochemistry

Author(s) -

Maskill Katie G.,

Knowles Jonathan P.,

Elliott Luke D.,

Alder Roger W.,

BookerMilburn Kevin I.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201208892

Subject(s) - bespoke , simplicity , chemistry , computer science , tricyclic , flow (mathematics) , service (business) , organic chemistry , philosophy , physics , business , advertising , mechanics , epistemology , marketing

Molecular acrobatics : Irradiation of N ‐butenyl‐substituted pyrroles that bear an electron‐withdrawing group leads to complex tricyclic aziridines through an unprecedented photocycloaddition–rearrangement sequence. Gram quantities of these complex products could be produced by using a bespoke flow reactor (see picture, FEP=fluorinated ethylene propylene).

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