Cooperative Catalysis through Noncovalent Interactions | Zendy

Tang Weijun | Zendy; Johnston Steven | Zendy; Iggo Jonathan A. | Zendy; Berry Neil G. | Zendy; Phelan Marie | Zendy; Lian Luyun | Zendy; Bacsa John | Zendy; Xiao Jianliang | Zendy

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Cooperative Catalysis through Noncovalent Interactions

Author(s) -

Tang Weijun,

Johnston Steven,

Iggo Jonathan A.,

Berry Neil G.,

Phelan Marie,

Lian Luyun,

Bacsa John,

Xiao Jianliang

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201208774

Subject(s) - iridium , chemistry , computer science , non covalent interactions , catalysis , ternary operation , phosphonate , combinatorial chemistry , nanotechnology , organic chemistry , materials science , molecule , hydrogen bond , programming language

One of four : A chiral phosphoric acid enables asymmetric hydrogenation of imines with an achiral iridium catalyst by virtue of noncovalent interactions. These interactions lead to the formation of a highly organized ternary complex, and the hydride is transferred highly enantioselectively.

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