Facile Carbon Monoxide Reduction at Intramolecular Frustrated Phosphane/Borane Lewis Pair Templates | Zendy

Sajid Muhammad | Zendy; Elmer LisaMaria | Zendy; Rosorius Christoph | Zendy; Daniliuc Constantin G. | Zendy; Grimme Stefan | Zendy; Kehr Gerald | Zendy; Erker Gerhard | Zendy

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Facile Carbon Monoxide Reduction at Intramolecular Frustrated Phosphane/Borane Lewis Pair Templates

Author(s) -

Sajid Muhammad,

Elmer LisaMaria,

Rosorius Christoph,

Daniliuc Constantin G.,

Grimme Stefan,

Kehr Gerald,

Erker Gerhard

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201208750

Subject(s) - frustrated lewis pair , borane , carbon monoxide , intramolecular force , chemistry , molecule , yield (engineering) , boranes , carbon fibers , lewis acids and bases , template , photochemistry , catalysis , stereochemistry , nanotechnology , organic chemistry , materials science , boron , composite number , metallurgy , composite material

A new reaction pathway : Carbon monoxide is readily reduced by Piers' borane at a frustrated Lewis pair (FLP) to yield a formylborane stabilized by the FLP (see picture). This reaction may be considered a typical example of efficient activation of a small molecule by a FLP.

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