Palladium‐Catalyzed Oxidative Acyloxylation/Carbocyclization of Allenynes | Zendy

Deng Youqian | Zendy; Bäckvall JanE. | Zendy

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Palladium‐Catalyzed Oxidative Acyloxylation/Carbocyclization of Allenynes

Author(s) -

Deng Youqian,

Bäckvall JanE.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201208718

Subject(s) - chemistry , palladium , allene , catalysis , oxidative phosphorylation , catalytic cycle , hydroxylation , transmetalation , alkene , oxidative addition , allylic rearrangement , benzoquinone , medicinal chemistry , bond cleavage , alkyne , combinatorial chemistry , organic chemistry , biochemistry , enzyme

New bonds : The title reaction provides access to synthetically useful acyloxylated vinylallenes where a new CC bond, a new CO bond, and a new allene structure are formed. Furthermore, an aerobic version of this transformation was realized using catalytic amounts of p ‐benzoquinone (BQ) together with catalytic amounts of cobalt salophen.

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