A Generic One‐Pot Route to Acyclic Two‐Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene | Zendy

Protchenko Andrey V. | Zendy; Schwarz Andrew D. | Zendy; Blake Matthew P. | Zendy; Jones Cameron | Zendy; Kaltsoyannis Nikolas | Zendy; Mountford Philip | Zendy; Aldridge Simon | Zendy

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A Generic One‐Pot Route to Acyclic Two‐Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene

Author(s) -

Protchenko Andrey V.,

Schwarz Andrew D.,

Blake Matthew P.,

Jones Cameron,

Kaltsoyannis Nikolas,

Mountford Philip,

Aldridge Simon

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201208554

Subject(s) - silicon , alkali metal , characterization (materials science) , chemistry , combinatorial chemistry , stereochemistry , organic chemistry , materials science , nanotechnology

Si in sight : A one‐pot, single‐step synthesis of an acyclic silylsilylene, Si{Si(SiMe 3 ) 3 }{N(SiMe 3 )Dipp} (Dipp=2,6‐ i Pr 2 C 6 H 3 ), from a silicon(IV) starting material is reported, together with evidence for a mechanism involving alkali metal silylenoid intermediates.

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