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Bottom‐Up Synthesis of Monodispersed Single‐Crystalline Cyano‐Bridged Coordination Polymer Nanoflakes
Author(s) -
Hu Ming,
Ishihara Shinsuke,
Yamauchi Yusuke
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201208501
Subject(s) - coordination polymer , nanoporous , non blocking i/o , materials science , morphology (biology) , polymer , chemical engineering , single crystal , flake , nanotechnology , crystallography , chemistry , catalysis , composite material , organic chemistry , geology , paleontology , engineering
A two‐dimensional morphology characterizes the nanoflakes that are obtained in the bottom‐up synthesis of a single‐crystalline coordination polymer, Ni(H 2 O) 2 [Ni(CN) 4 ]⋅ x H 2 O. The 10 nm‐thick nanoflakes are well‐dispersed in solution and have a very high accessible surface area (240 m 2 g −1 ). Thermal treatment leads to nanoporous NiO with retention of the original flake morphology.