Syntheses and Structural Studies of Tris( N ‐phenothiazinyl)borane and Its Radical Cation | Zendy

Suzuki Shuichi | Zendy; Yoshida Kohei | Zendy; Kozaki Masatoshi | Zendy; Okada Keiji | Zendy

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Syntheses and Structural Studies of Tris( N ‐phenothiazinyl)borane and Its Radical Cation

Author(s) -

Suzuki Shuichi,

Yoshida Kohei,

Kozaki Masatoshi,

Okada Keiji

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201208392

Subject(s) - borane , tris , chemistry , phenothiazine , radical ion , combinatorial chemistry , computer science , organic chemistry , catalysis , medicine , ion , biochemistry , pharmacology

A radical comparison : The neutral ( 1 ) and radical cation ( 1 .+ ) forms of tris( N ‐phenothiazinyl)borane were prepared and their molecular structures and spectral properties investigated. The results established that 1 .+ possessed a localized radical cation on one of the phenothiazine (PTZ) rings. The crystal structure of 1 .+ showed elongation of the BN bond bound to the PTZ .+ ring (BN1: 1.53 Å).

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