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Total Syntheses of Complanadines A and B
Author(s) -
Zhao Le,
Tsukano Chihiro,
Kwon Eunsang,
Takemoto Yoshiji,
Hirama Masahiro
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201208297
Subject(s) - computer science , world wide web , nice , information retrieval , chemistry , programming language
Twice as nice : Total syntheses of dimeric alkaloids, (−)‐complanadines A ( 1 ) and B ( 2 ), were achieved from (−)‐lycodine. The unsymmetrical motif was assembled through direct arylation of the pyridine N ‐oxide. The absolute configuration and specific rotations of complanadines A and B were identified. Cbz=Benzyloxycarbonyl.
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