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Straightforward Synthetic Access to gem ‐Diaurated and Digold σ,π‐Acetylide Species
Author(s) -
GómezSuárez Adrián,
Dupuy Stéphanie,
Slawin Alexandra M. Z.,
Nolan Steven P.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201208234
Subject(s) - acetylide , computer science , scheme (mathematics) , chemistry , combinatorial chemistry , information retrieval , medicinal chemistry , mathematics , mathematical analysis
The more the merrier : Following previous investigations on the synthesis of organogold complexes by using [Au(IPr)(OH)], a high‐yielding straightforward methodology for the synthesis of gem ‐diaurated and σ,π‐acetylide species via a dinuclear gold hydroxide complex [{Au(IPr)} 2 (μ‐OH)][BF 4 ] (see scheme) has now been developed.
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