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Dynamically Deformable Cube‐like Hydrogen‐Bonding Networks in Water‐Responsive Diamondoid Porous Organic Salts
Author(s) -
Yamamoto Atsushi,
Hamada Tomoya,
Hisaki Ichiro,
Miyata Mikiji,
Tohnai Norimitsu
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201208153
Subject(s) - diamondoid , hydrogen bond , cube (algebra) , supramolecular chemistry , fluorescence , water cluster , molecule , porosity , materials science , transformation (genetics) , cluster (spacecraft) , chemical physics , nanotechnology , chemistry , computer science , composite material , physics , geometry , organic chemistry , mathematics , biochemistry , quantum mechanics , gene , programming language
Just add water : A cube‐like hydrogen‐bonding network in a fluorescent supramolecular cluster dynamically deforms upon the specific addition of a water molecule. The deformation is amplified through the conformational change of the cluster to result in the transformation of host frameworks. This transformation provides water‐responsive guest‐exclusion and fluorescent‐modulation behaviors.