A Tetracarbene–Oxoiron(IV) Complex | Zendy

Meyer Steffen | Zendy; Klawitter Iris | Zendy; Demeshko Serhiy | Zendy; Bill Eckhard | Zendy; Meyer Franc | Zendy

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A Tetracarbene–Oxoiron(IV) Complex

Author(s) -

Meyer Steffen,

Klawitter Iris,

Demeshko Serhiy,

Bill Eckhard,

Meyer Franc

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201208044

Subject(s) - bioinorganic chemistry , variety (cybernetics) , chemistry , key (lock) , computer science , library science , stereochemistry , artificial intelligence , computer security

Bioinspired organometallic chemistry : An oxoiron(IV) unit has been trapped within a macrocyclic tetracarbene ligand, merging a key bioinorganic intermediate with a popular organometallic scaffold (see picture). The stability of the new complex has allowed its characterization by a variety of methods, which show a strong σ‐donating tetracarbene coordination leading to an S =1 ground state and unusual properties of the oxoiron(IV) species.

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