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Decarboxylative Cross‐Coupling of Mesylates Catalyzed by Copper/Palladium Systems with Customized Imidazolyl Phosphine Ligands
Author(s) -
Song Bingrui,
Knauber Thomas,
Gooßen Lukas J.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201208025
Subject(s) - phosphine , aryl , palladium , combinatorial chemistry , class (philosophy) , chemistry , coupling (piping) , catalysis , computer science , medicinal chemistry , organic chemistry , materials science , alkyl , metallurgy , artificial intelligence
The activation of the inert CO bonds in mesylates through the use of a new class of imidazolyl phosphines allows the decarboxylative coupling of aryl mesylates as well as polysubstituted alkenyl mesylates. Variation of the ligands leads to two complementary methods providing the corresponding biaryls and polysubstituted olefins in good yields.