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The Inherent Single‐Molecule Magnet Character of Trivalent Uranium
Author(s) -
Moro Fabrizio,
Mills David P.,
Liddle Stephen T.,
van Slageren Joris
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201208015
Subject(s) - uranium , computer science , magnet , character (mathematics) , relaxation (psychology) , single molecule magnet , service (business) , range (aeronautics) , magnetization , homogeneous space , chemistry , information retrieval , materials science , physics , nuclear physics , psychology , mathematics , business , quantum mechanics , social psychology , geometry , marketing , magnetic field , composite material
Uranium magnets : Three uranium(III) complexes with distinctly different structures and compositions are all shown to display slow relaxation of the magnetization. This study greatly expands the range of slowly relaxing uranium complexes, and demonstrates that this behavior is not limited to specific ligand types or molecular symmetries (see picture).