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Desymmetrization Catalyzed by Transition‐Metal Complexes: Enantioselective Formation of Silicon‐Stereogenic Silanes
Author(s) -
Xu LiWen
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201207932
Subject(s) - desymmetrization , silanes , stereocenter , enantioselective synthesis , silicon , chemistry , catalysis , organic chemistry , stereochemistry , silane
Prochiral silanes : Recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition‐metal complexes in the stereoselective formation of silicon‐stereogenic silanes. These methods offer new possibilities for asymmetric synthesis of any functionalized chiral silanes that possess tetraorganosilicon stereocenters.