Nonlinear Amplification of a Supramolecular Complex at a Multivalent Interface | Zendy

Hsu ShuHan | Zendy; Yilmaz M. Deniz | Zendy; Reinhoudt David N. | Zendy; Velders Aldrik H. | Zendy; Huskens Jurriaan | Zendy

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Nonlinear Amplification of a Supramolecular Complex at a Multivalent Interface

Author(s) -

Hsu ShuHan,

Yilmaz M. Deniz,

Reinhoudt David N.,

Velders Aldrik H.,

Huskens Jurriaan

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201207647

Subject(s) - monolayer , supramolecular chemistry , cyclodextrin , molecule , chemistry , carboxylate , ligand (biochemistry) , self assembly , crystallography , stereochemistry , receptor , organic chemistry , biochemistry

Competition with a monovalent cyclodextrin host (blue cones) in solution drives the multivalent binding of a Eu 3+ complex and a sensitizer molecule to cyclodextrin monolayers through a nonlinear self‐assembly process. Adamantyl groups (light‐blue spheres) are attached to the EDTA ligand (black) and the antenna molecule (orange), which has a carboxylate group for coordination to the Eu 3+ ion (yellow or red in free or complexed form, respectively).

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