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Self‐Assembling Decacyclene Triimides Prepared through a Regioselective Hextuple Friedel–Crafts Carbamylation
Author(s) -
Pho Toan V.,
Toma Francesca M.,
Chabinyc Michael L.,
Wudl Fred
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201207608
Subject(s) - friedel–crafts reaction , regioselectivity , nanotechnology , computer science , chemistry , materials science , organic chemistry , catalysis
Molecular electronics : A hextuple Friedel–Crafts carbamylation is reported in the synthesis of the electroactive decacyclene triimides (see picture). These triimides self‐assemble into different nanostructures through modification of the alkyl substituents and are promising n‐type materials for organic semiconducting devices.