Highly Enantioselective [3+3] Cycloaddition of Aromatic Azomethine Imines with Cyclopropanes Directed by π–π Stacking Interactions | Zendy

Zhou YouYun | Zendy; Li Jun | Zendy; Ling Lin | Zendy; Liao SaiHu | Zendy; Sun XiuLi | Zendy; Li YuXue | Zendy; Wang LiJia | Zendy; Tang Yong | Zendy

Premium

Highly Enantioselective [3+3] Cycloaddition of Aromatic Azomethine Imines with Cyclopropanes Directed by π–π Stacking Interactions

Author(s) -

Zhou YouYun,

Li Jun,

Ling Lin,

Liao SaiHu,

Sun XiuLi,

Li YuXue,

Wang LiJia,

Tang Yong

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201207576

Subject(s) - enantioselective synthesis , stacking , cycloaddition , stereoselectivity , chemistry , computer science , combinatorial chemistry , catalysis , aromaticity , stereochemistry , computational chemistry , organic chemistry , molecule

Designing armory : The side‐arm‐modified In‐TOX/Ni II complex was identified as a highly efficient and stereoselective catalyst for the [3+3] cycloaddition of aromatic azomethine imines with cyclopropanes (see picture). Density functional calculations and control experiments revealed that the directing effect of the side arm through π interactions is crucial to the stereochemical control.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research