2,2‐Bipyridine Complexes of Antimony: Sequential Fluoride Ion Abstraction from SbF 3  by Exploiting the Fluoride Ion Affinity of Me 3 Si + | Zendy

Chitnis Saurabh S. | Zendy; Burford Neil | Zendy; Ferguson Michael J. | Zendy

Premium

2,2‐Bipyridine Complexes of Antimony: Sequential Fluoride Ion Abstraction from SbF 3 by Exploiting the Fluoride Ion Affinity of Me 3 Si +

Author(s) -

Chitnis Saurabh S.,

Burford Neil,

Ferguson Michael J.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201207529

Subject(s) - fluoride , abstraction , antimony , ion , lewis acids and bases , chemistry , bipyridine , yield (engineering) , computer science , inorganic chemistry , crystallography , organic chemistry , physics , crystal structure , thermodynamics , philosophy , epistemology , catalysis

Gas driven : A high‐yield approach to sequential fluoride ion abstraction from SbF 3 in the presence of 2,2′‐bipyridine gives a series of complexes containing [SbF 2 ] + , [SbF] 2+ , and [Sb] 3+ (see figure) acceptors. The thermodynamically favorable rapid elimination of gaseous Me 3 SiF provides a potentially general approach to enhance the Lewis acidity and coordination chemistry of p‐block centers.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research