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Sequence‐Dependent Assembly to Control Molecular Interface Properties
Author(s) -
de Ruiter Graham,
Lahav Michal,
Keisar Hodaya,
van der Boom Milko E.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201207467
Subject(s) - isostructural , sequence (biology) , computer science , interface (matter) , variation (astronomy) , similarity (geometry) , control (management) , information retrieval , service (business) , charge (physics) , nanotechnology , materials science , chemistry , crystallography , physics , artificial intelligence , biochemistry , economy , bubble , quantum mechanics , maximum bubble pressure method , parallel computing , astrophysics , crystal structure , economics , image (mathematics)
Variation's what you need : Variation of the assembly sequence in which layers of two isostructural metal complexes are built up leads to molecular materials with electrochemical properties that depend on the assembly sequence. These properties vary from reversible electron transfer to unidirectional current flows and even charge trapping. The sequence‐dependent assembly strategy has implications for various disciplines that involve self‐assembly.