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[(μ‐H) 3 Re 3 (CO) 9 (η 2 ,η 2 ,η 2 ‐Sc 2 C 2 @ C 3 v (8)‐C 82 )]: Face‐Capping Cluster Complex of an Endohedral Fullerene
Author(s) -
Chen ChiaHsiang,
Yeh WenYann,
Liu YiHung,
Lee GeneHsiang
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201207261
Subject(s) - crystallography , infrared spectroscopy , spectroscopy , infrared , x ray crystallography , chemistry , cluster (spacecraft) , fullerene , diffraction , physics , analytical chemistry (journal) , optics , organic chemistry , chromatography , quantum mechanics , computer science , programming language
Like a miniature trophy , the complex pictured was obtained as the sole product from the reaction of Sc 2 C 2 @ C 3 v (8)‐C 82 and [(μ‐H) 3 Re 3 (CO) 11 (NCMe)] and characterized by IR, visible/near‐infrared, and NMR spectroscopy, mass spectrometry, and X‐ray diffraction. Coordination of the Re 3 cluster to the unique hexagon oriented perpendicular to the C 3 axis of the fullerene core altered the geometry and electronic properties of Sc 2 C 2 @ C 3 v (8)‐C 82 .
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