From Olefins to Alcohols: Efficient and Regioselective Ruthenium‐Catalyzed Domino Hydroformylation/Reduction Sequence | Zendy

Fleischer Ivana | Zendy; Dyballa Katrin Marie | Zendy; Jennerjahn Reiko | Zendy; Jackstell Ralf | Zendy; Franke Robert | Zendy; Spannenberg Anke | Zendy; Beller Matthias | Zendy

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From Olefins to Alcohols: Efficient and Regioselective Ruthenium‐Catalyzed Domino Hydroformylation/Reduction Sequence

Author(s) -

Fleischer Ivana,

Dyballa Katrin Marie,

Jennerjahn Reiko,

Jackstell Ralf,

Franke Robert,

Spannenberg Anke,

Beller Matthias

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201207133

Subject(s) - hydroformylation , ruthenium , domino , regioselectivity , chemistry , sequence (biology) , phosphine , organic chemistry , catalysis , reduction (mathematics) , computer science , combinatorial chemistry , rhodium , mathematics , biochemistry , geometry

Exploring the alternatives : Ruthenium imidazoyl phosphine complexes catalyze the domino hydroformylation/reduction of alkenes to alcohols in good yields and with good selectivities (see scheme). Linear aliphatic alcohols are synthesized under reaction conditions typically used in industrial hydroformylations.

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