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Dienamine‐Mediated Inverse‐Electron‐Demand Hetero‐Diels–Alder Reaction by Using an Enantioselective H‐Bond‐Directing Strategy
Author(s) -
Albrecht Łukasz,
Dickmeiss Gustav,
Weise Christian F.,
RodríguezEscrich Carles,
Jørgensen Karl Anker
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201207122
Subject(s) - stereocenter , enantioselective synthesis , bifunctional , inverse , chemistry , computer science , stereochemistry , organic chemistry , philosophy , catalysis , linguistics
Giving directions : Optically active dihydropyrans bearing three contiguous stereogenic centers can be efficiently prepared by the title reaction. High stereo‐ and regiocontrol can be achieved by employing a bifunctional H‐bond‐directing aminocatalyst.
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