Hydrogenation of a Rhodium Peroxido Complex by Formate Derivatives: Mechanistic Studies and the Catalytic Formation of H 2 O 2  from O 2 | Zendy

Meier Gregor | Zendy; Braun Thomas | Zendy

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Hydrogenation of a Rhodium Peroxido Complex by Formate Derivatives: Mechanistic Studies and the Catalytic Formation of H 2 O 2 from O 2

Author(s) -

Meier Gregor,

Braun Thomas

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201207073

Subject(s) - rhodium , formate , catalysis , hydrogen peroxide , ammonium formate , chemistry , yield (engineering) , photochemistry , hydrogen , inorganic chemistry , materials science , organic chemistry , acetonitrile , metallurgy

Hydrogenation of dioxygen : The rhodium peroxido complex 1 , which can be prepared from 2 and dioxygen, can be reduced with dihydrogen sources to yield hydrogen peroxide. In a catalytic experiment, hydrogen peroxide is produced from dioxygen and ammonium formate under ambient conditions in the presence of 1 (see scheme).

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